Estudiantes La Plata 1-1 São Paulo/SP *
| 20.07.2006 | São Paulo/SP | 1-0/p.4-3 | Estudiantes La Plata | |
| 11.05.2006 | Estudiantes La Plata | 1-0 | São Paulo/SP | |
*Guadalajara Chivas 2-1 Vélez Sársfield
| 21.07.2006 | Vélez Sársfield | 1-2 | Guadalajara Chivas | |
| 10.05.2006 | Guadalajara Chivas | 0-0 | Vélez Sársfield | |
LDU Quito 2-3 Internacional/RS *
| 20.07.2006 | Internacional/RS | 2-0 | LDU Quito | |
| 11.05.2006 | LDU Quito | 2-1 | Internacional/RS | |
River Plate 3-5 Club Libertad *
| 19.07.2006 | Club Libertad | 3-1 | River Plate | |
| 12.05.2006 | River Plate | 2-2 | Club Libertad | |