*CA Lanús 3-1 River Plate
| 07.11.2013 | River Plate | 1-3 | CA Lanús | |
| 30.10.2013 | CA Lanús | 0-0 | River Plate | |
*Club Libertad 2-1 Itagüí Ditaires
| 08.11.2013 | Itagüí Ditaires | 1-0 | Club Libertad | |
| 01.11.2013 | Club Libertad | 2-0 | Itagüí Ditaires | |
*Ponte Preta/SP 2-0 Vélez Sársfield
| 07.11.2013 | Vélez Sársfield | 0-2 | Ponte Preta/SP | |
| 31.10.2013 | Ponte Preta/SP | 0-0 | Vélez Sársfield | |
*São Paulo/SP 3-2 Atlético Nacional
| 07.11.2013 | Atlético Nacional | 0-0 | São Paulo/SP | |
| 31.10.2013 | São Paulo/SP | 3-2 | Atlético Nacional | |