*Campinense/PB 2-1 CSA/AL
| 09.09.2012 | CSA/AL | 0-0 | Campinense/PB | |
| 01.09.2012 | Campinense/PB | 2-1 | CSA/AL | |
Juventude/RS 3-4 Cianorte/PR *
| 09.09.2012 | Cianorte/PR | 3-0 | Juventude/RS | |
| 02.09.2012 | Juventude/RS | 3-1 | Cianorte/PR | |
Ceilândia/DF 1-2 Friburguense/RJ *
| 09.09.2012 | Friburguense/RJ | 2-1 | Ceilândia/DF | |
| 02.09.2012 | Ceilândia/DF | 0-0 | Friburguense/RJ | |
*Mogi Mirim/SP 2-2 Metropolitano/SC
| 09.09.2012 | Metropolitano/SC | 1-2 | Mogi Mirim/SP | |
| 02.09.2012 | Mogi Mirim/SP | 0-1 | Metropolitano/SC | |
Nacional/MG 2-2 CRAC/GO *
| 09.09.2012 | CRAC/GO | 1-0 | Nacional/MG | |
| 02.09.2012 | Nacional/MG | 2-1 | CRAC/GO | |
Sousa/PB 0-3 Baraúnas/RN *
| 09.09.2012 | Baraúnas/RN | 2-0 | Sousa/PB | |
| 02.09.2012 | Sousa/PB | 0-1 | Baraúnas/RN | |
Vilhena/RO 3-6 Sampaio Correa/MA *
| 13.09.2012 | Sampaio Correa/MA | 4-1 | Vilhena/RO | |
| 03.09.2012 | Vilhena/RO | 2-2 | Sampaio Correa/MA | |