| 03.11.2012 | |||
| 16:00 | Airdrie United | 2-2 | Raith Rovers |
| 16:00 | Albion Rovers | 1-1 | Greenock Morton |
| 16:00 | Ayr United | 2-1 | Clachnacuddin |
| 16:00 | Brechin City | 2-2 | Bonnyrigg Rose |
| 16:00 | Buckie Thistle | 0-1 | Turriff United |
| 16:00 | Dumbarton FC | 4-1 | East Stirlingshire |
| 16:00 | Edinburgh City | 0-2 | Queen of the South |
| 16:00 | Elgin City | 5-1 | East Fife |
| 16:00 | Forfar Athletic | 3-3 | Nairn County |
| 16:00 | Inverurie Loco Works | 3-3 | Arbroath FC |
| 16:00 | Partick Thistle | 2-1 | Cove Rangers |
| 16:00 | Rangers FC | 7-0 | Alloa Athletic |
| 16:00 | Stenhousemuir FC | 1-1 | Berwick Rangers |
| 16:00 | Stirling Albion | 0-1 | Deveronvale FC |
| 16:00 | Stranraer FC | 1-1 | Queen's Park FC |
| 15:00 | Cowdenbeath | 8-1 | Vale of Leithen |
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