| 21.05.2014 | |||
| 14:00 | BEC Tero Sasana | 1-2 | Nakhon Ratchasima |
| 14:00 | Chiangrai United | 2-0 | Army United |
| 14:00 | Osotspa Saraburi | 0-3 | Muang Thong United |
| 14:00 | Police United (THA) | 0-1 | Chonburi FC |
| 14:00 | Ratchaburi FC | 5-3 AET | Chiangmai FC |
| 14:00 | TOT SC | 2-1 | Ayutthaya FC |
| 13:30 | Siam Navy | 2-3 | Bangkok Glass |
| 13:00 | Bangkok FC | 2-0 | Air Force Central |
| 13:00 | Buriram United | 2-1 | Chainat FC |
| 13:00 | Khonkaen FC | 0-1 | Bangkok United |
| 13:00 | Nakhon Pathom Utd | 0-1 | Suphanburi FC |
| 13:00 | PTT Rayong FC | 3-2 | Thai Honda FC |
| 13:00 | Sisaket FC | 2-0 | Ang Thong FC |
| 13:00 | Songkhla United | 0-0/p.4-3 | Singhtarua FC |
| 10:00 | Nakhon Nayok | 1-1/p.2-4 | Trat FC |
| 10:00 | TTM Customs | 1-2 | Samut Songkhram |
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