AS Monaco 3-4 PSV Eindhoven *
| 09.08.2022 | PSV Eindhoven | 3-2 AET | AS Monaco | |
| 02.08.2022 | AS Monaco | 1-1 | PSV Eindhoven | |
*Dynamo Kyiv 3-1 Sturm Graz
| 09.08.2022 | Sturm Graz | 1-2 AET | Dynamo Kyiv | |
| 03.08.2022 | Dynamo Kyiv | 1-0 | Sturm Graz | |
*SL Benfica 7-2 FC Midtjylland
| 09.08.2022 | FC Midtjylland | 1-3 | SL Benfica | |
| 02.08.2022 | SL Benfica | 4-1 | FC Midtjylland | |
Union Saint-Gilloise 2-3 Rangers FC *
| 09.08.2022 | Rangers FC | 3-0 | Union Saint-Gilloise | |
| 02.08.2022 | Union Saint-Gilloise | 2-0 | Rangers FC | |