Central Córdoba SdE 0-3 Juventud Unida SL *
| 10.05.2014 | Juventud Unida SL | 1-0 | Central Córdoba SdE | |
| 04.05.2014 | Central Córdoba SdE | 0-2 | Juventud Unida SL | |
Chaco For Ever 2-5 Juventud Unida (G) *
| 10.05.2014 | Juventud Unida (G) | 4-1 | Chaco For Ever | |
| 05.05.2014 | Chaco For Ever | 1-1 | Juventud Unida (G) | |
*CS Estudiantes (SL) 5-4 Def. Belgrano (VR)
| 10.05.2014 | Def. Belgrano (VR) | 2-4 | CS Estudiantes (SL) | |
| 04.05.2014 | CS Estudiantes (SL) | 1-2 | Def. Belgrano (VR) | |
Gimnasia y Tiro 3-3 Guillermo Brown *
| 10.05.2014 | Guillermo Brown | 2-1 | Gimnasia y Tiro | |
| 04.05.2014 | Gimnasia y Tiro | 2-1 | Guillermo Brown | |
Libertad Sunchales 2-4 San Martín Tucumán *
| 11.05.2014 | San Martín Tucumán | 2-1 | Libertad Sunchales | |
| 04.05.2014 | Libertad Sunchales | 1-2 | San Martín Tucumán | |
Club Cipolletti 2-3 Tiro Federal *
| 10.05.2014 | Tiro Federal | 3-0 | Club Cipolletti | |
| 04.05.2014 | Club Cipolletti | 2-0 | Tiro Federal | |