*Jorge Wilstermann 5-1 Universitario Sucre
| 24.07.2016 | Universitario Sucre | 1-1 | Jorge Wilstermann | |
| 22.07.2016 | Jorge Wilstermann | 4-0 | Universitario Sucre | |
*Oriente Petrolero 1-1 Sport Boys Warnes
| 24.07.2016 | Sport Boys Warnes | 0-0/p.4-5 | Oriente Petrolero | |
| 21.07.2016 | Oriente Petrolero | 1-1 | Sport Boys Warnes | |
*CD San José 2-3 Petrolero Yacuiba
| 24.07.2016 | Petrolero Yacuiba | 2-0/p.4-5 | CD San José | |
| 21.07.2016 | CD San José | 2-1 | Petrolero Yacuiba | |
The Strongest 2-5 Real Potosí *
| 24.07.2016 | Real Potosí | 3-1 | The Strongest | |
| 21.07.2016 | The Strongest | 1-2 | Real Potosí | |