Blooming 1-3 Oriente Petrolero *
| 15.07.2014 | Oriente Petrolero | 2-0 | Blooming | |
| 11.07.2014 | Blooming | 1-1 | Oriente Petrolero | |
*The Strongest 3-3 Bolívar
| 15.07.2014 | Bolívar | 1-2/p.5-6 | The Strongest | |
| 10.07.2014 | The Strongest | 1-2 | Bolívar | |
*Universitario Sucre 2-5 CD San José
| 12.07.2014 | CD San José | 4-0/p.2-4 | Universitario Sucre | |
| 10.07.2014 | Universitario Sucre | 2-1 | CD San José | |
*Jorge Wilstermann 5-2 Club Aurora
| 13.07.2014 | Club Aurora | 1-3 | Jorge Wilstermann | |
| 10.07.2014 | Jorge Wilstermann | 2-1 | Club Aurora | |
Nacional Potosí 1-2 Real Potosí *
| 13.07.2014 | Real Potosí | 1-0 | Nacional Potosí | |
| 10.07.2014 | Nacional Potosí | 1-1 | Real Potosí | |
CD Guabirá 1-3 Sport Boys Warnes *
| 12.07.2014 | Sport Boys Warnes | 2-0 | CD Guabirá | |
| 10.07.2014 | CD Guabirá | 1-1 | Sport Boys Warnes | |