UD Poblense 2-3 CD Binissalem *
| 25.09.2013 | CD Binissalem | 2-0 | UD Poblense | |
| 18.09.2013 | UD Poblense | 2-1 | CD Binissalem | |
*CD Castellón 1-0 Atlético Saguntino
| 25.09.2013 | Atlético Saguntino | 0-1 | CD Castellón | |
| 18.09.2013 | CD Castellón | 0-0 | Atlético Saguntino | |
*Cultural Leonesa 4-2 CD Guijuelo
| 02.10.2013 | CD Guijuelo | 0-2 | Cultural Leonesa | |
| 25.09.2013 | Cultural Leonesa | 2-2 | CD Guijuelo | |
CD Minera 2-2 Cartagena FC *
| 25.09.2013 | Cartagena FC | 0-0 | CD Minera | |
| 18.09.2013 | CD Minera | 2-2 | Cartagena FC | |
Alondras CF 1-3 CD Ourense *
| 26.09.2013 | CD Ourense | 2-0 | Alondras CF | |
| 19.09.2013 | Alondras CF | 1-1 | CD Ourense | |
UB Conquense 2-3 CD Puertollano *
| 25.09.2013 | CD Puertollano | 2-2 | UB Conquense | |
| 11.09.2013 | UB Conquense | 0-1 | CD Puertollano | |
*CD Plus Ultra 2-2 CF Molina
| 25.09.2013 | CF Molina | 2-1 | CD Plus Ultra | |
| 18.09.2013 | CD Plus Ultra | 1-0 | CF Molina | |
Cartagena FC 0-3 El Palmar CF-EG *
| 09.10.2013 | El Palmar CF-EG | 2-0 | Cartagena FC | |
| 02.10.2013 | Cartagena FC | 0-1 | El Palmar CF-EG | |
*El Palmar CF-EG 5-2 Mar Menor CF
| 25.09.2013 | Mar Menor CF | 2-4 | El Palmar CF-EG | |
| 18.09.2013 | El Palmar CF-EG | 1-0 | Mar Menor CF | |
*Recreativo Granada 6-2 Loja CD
| 25.09.2013 | Loja CD | 2-0 | Recreativo Granada | |
| 18.09.2013 | Recreativo Granada | 6-0 | Loja CD | |
*Marino de Luanco 3-0 UP Langreo
| 09.10.2013 | UP Langreo | 0-0 | Marino de Luanco | |
| 04.09.2013 | Marino de Luanco | 3-0 | UP Langreo | |
*UD Alzira 4-1 Ontinyent 1931 CF
| 26.09.2013 | Ontinyent 1931 CF | 0-0 | UD Alzira | |
| 18.09.2013 | UD Alzira | 4-1 | Ontinyent 1931 CF | |
Rayo Cantabria 0-2 SD Laredo *
| 18.09.2013 | SD Laredo | 2-0 | Rayo Cantabria | |
| 04.09.2013 | Rayo Cantabria | 0-0 | SD Laredo | |
AE Prat 4-5 RCD Espanyol B *
| 25.09.2013 | RCD Espanyol B | 2-3 | AE Prat | |
| 18.09.2013 | AE Prat | 1-3 | RCD Espanyol B | |
SD Formentera 1-6 RCD Mallorca B *
| 25.09.2013 | RCD Mallorca B | 2-0 | SD Formentera | |
| 18.09.2013 | SD Formentera | 1-4 | RCD Mallorca B | |
Sporting Gijón B 1-5 Real Avilés
| 11.09.2013 | Real Avilés | 4-1 | Sporting Gijón B | |
| 05.09.2013 | Sporting Gijón B | 0-1 | Real Avilés | |
Santoña CF 2-4 Gimn. Torrelavega
| 18.09.2013 | Gimn. Torrelavega | 2-1 | Santoña CF | |
| 04.09.2013 | Santoña CF | 1-2 | Gimn. Torrelavega | |
*SD Compostela 5-4 Pontevedra CF
| 03.10.2013 | Pontevedra CF | 3-3 | SD Compostela | |
| 18.09.2013 | SD Compostela | 2-1 | Pontevedra CF | |
UD Almansa 3-1 CDEEF Zona 5
| 11.09.2013 | CDEEF Zona 5 | 1-1 | UD Almansa | |
| 04.09.2013 | UD Almansa | 2-0 | CDEEF Zona 5 | |
Villacarrillo CF 2-4 UD Almeria B *
| 25.09.2013 | UD Almeria B | 2-1 | Villacarrillo CF | |
| 11.09.2013 | Villacarrillo CF | 1-2 | UD Almeria B | |
CD Plus Ultra 1-6 Yeclano Deportivo *
| 09.10.2013 | Yeclano Deportivo | 2-1 | CD Plus Ultra | |
| 02.10.2013 | CD Plus Ultra | 0-4 | Yeclano Deportivo | |
Edeco Fortuna 1-7 Yeclano Deportivo *
| 26.09.2013 | Yeclano Deportivo | 4-1 | Edeco Fortuna | |
| 18.09.2013 | Edeco Fortuna | 0-3 | Yeclano Deportivo | |
Zamora CF 3-4 Arandina CF *
| 01.10.2013 | Arandina CF | 2-2 | Zamora CF | |
| 25.09.2013 | Zamora CF | 1-2 | Arandina CF | |