*Atlético Madrid (W) 2-1 Athletic Bilbao (W)
| 19.05.2013 | Athletic Bilbao (W) | 1-1 | Atlético Madrid (W) | |
| 12.05.2013 | Atlético Madrid (W) | 1-0 | Athletic Bilbao (W) | |
Rayo Vallecano (W) 0-2 FC Barcelona (W) *
| 19.05.2013 | FC Barcelona (W) | 2-0 AET | Rayo Vallecano (W) | |
| 12.05.2013 | Rayo Vallecano (W) | 0-0 | FC Barcelona (W) | |
RCD Espanyol (W) 2-3 Levante UD (W) *
| 18.05.2013 | Levante UD (W) | 2-1 | RCD Espanyol (W) | |
| 12.05.2013 | RCD Espanyol (W) | 1-1 | Levante UD (W) | |
Sant Gabriel (W) 4-4 Prainsa Zaragoza (W) *
| 19.05.2013 | Prainsa Zaragoza (W) | 1-1 | Sant Gabriel (W) | |
| 12.05.2013 | Sant Gabriel (W) | 3-3 | Prainsa Zaragoza (W) | |