Athletic Bilbao 0-5 Real Madrid
| 12.01.2006 | Real Madrid | 4-0 | Athletic Bilbao | |
| 03.01.2006 | Athletic Bilbao | 0-1 | Real Madrid | |
Atlético Madrid 2-3 Real Zaragoza
| 18.01.2006 | Real Zaragoza | 2-2 | Atlético Madrid | |
| 11.01.2006 | Atlético Madrid | 0-1 | Real Zaragoza | |
Deportivo La Coruña 4-2 CA Osasuna
| 11.01.2006 | CA Osasuna | 2-1 | Deportivo La Coruña | |
| 04.01.2006 | Deportivo La Coruña | 3-0 | CA Osasuna | |
Zamora CF 1-9 FC Barcelona
| 11.01.2006 | FC Barcelona | 6-0 | Zamora CF | |
| 03.01.2006 | Zamora CF | 1-3 | FC Barcelona | |
Getafe CF 3-4 RCD Espanyol
| 11.01.2006 | RCD Espanyol | 3-3 | Getafe CF | |
| 04.01.2006 | Getafe CF | 0-1 | RCD Espanyol | |
Celta de Vigo 1-1 Real Betis
| 11.01.2006 | Real Betis | 0-0 | Celta de Vigo | |
| 04.01.2006 | Celta de Vigo | 1-1 | Real Betis | |
Cádiz CF 3-2 Sevilla FC
| 11.01.2006 | Sevilla FC | 0-0 | Cádiz CF | |
| 04.01.2006 | Cádiz CF | 3-2 | Sevilla FC | |
Villarreal CF 0-3 Valencia CF
| 11.01.2006 | Valencia CF | 1-0 | Villarreal CF | |
| 04.01.2006 | Villarreal CF | 0-2 | Valencia CF | |