| 09.06.2012 | ||||
| 13:00 | LC Round 1 | Kamphaengphet FC | 0-0/p.2-4 | Chiangrai United |
| 13:00 | LC Round 1 | Phattalung FC | 2-1 | Police United (THA) |
| 13:00 | LC Round 1 | Phichit FC | 0-2 | Songkhla FC |
| 13:00 | LC Round 1 | Rayong FC | 2-2/p.4-5 | TTM Chiangmai |
| 12:45 | LC Round 1 | Kalasin FC | 0-1 | Samut Songkhram |
| 12:30 | LC Round 1 | Lopburi City FC | 1-1/p.4-3 | PTT Rayong FC |
| 12:30 | LC Round 1 | Prachuap Khiri Khan | 1-2 | Pattaya United |
| 12:30 | LC Round 1 | Trat FC | 2-0 | Bangkok FC |
| 12:00 | LC Round 1 | Nakhon Si Thammarat | 0-1 | Chonburi FC |
| 12:00 | LC Round 1 | Ratchaburi FC | 4-3 AET | Chainat FC |
| 12:00 | LC Round 1 | Sisaket United FC | 0-2 | Osotspa Saraburi |
| 12:00 | LC Round 1 | Yala FC | 0-1 | Thai Port FC |
| 11:00 | LC Round 1 | Thai Honda FC | 1-2 | Muang Thong United |
| 10:30 | LC Round 1 | Customs United FC | 3-2 | BBCU FC |
| 10:30 | LC Round 1 | Kasetsart FC | 4-0 | Esan United |
| 10:30 | LC Round 1 | Paknampho NSRU | 3-1 AET | Army United |
| 10:30 | LC Round 1 | RBAC BEC Tero Sasana | 3-4 | Bangkok Glass |
| 10:30 | LC Round 1 | Sa Kaeo United | 0-1 | Phuket FC |
| 00:00 | LC Round 1 | Pattani FC | 3-0 W.O. | Saraburi FC |
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